The overwhelming majority of hydraulic components and systems are designed to use oil-based hydraulic fluids. No wonder; these fluids rarely present significant operating, safety, or maintenance problems. Unfortunately, there are circumstances where using oil-based fluid should be avoided. One common fluid power application is in an environment with potential ignition sources &emdash; an open flame, sparks, or hot metal. In these environments, a leak spraying from a high-pressure hydraulic system could cause a serious fire and result in major property damage, personnel injury, or even death.

Even though most oil-based hydraulic fluids have relatively high flash/fire points (>300° F), small leaks in a high-pressure system can produce a finely atomized spray that can travel significant distances. If an ignition source is encountered, complete ignition of the spray envelope can occur. The alternative is to use a hydraulic fluid that eliminates or significantly reduces this hazard: any of several fire-resistant hydraulic fluids (FRHFs).

The decision to purchase a higher-priced FRHF is perhaps analogous to our income tax dilemma this month; you don't want to pay it, but the alternative is worse. However, there is more to know about FRHFs than just price; there are significant chemical and performance differences that must be understood before specifying a FRHF for any given application. To address this need, this article will briefly review the evolution of FRHFs, the types of fluids that are commercially available, and the advantages and disadvantages associated with each.

How far we've come

The history of FRHF is relatively simple and has been one of slow evolution. As the name implies, the original fluid medium in hydraulic applications was water, and it offered the highest degree of fire resistance possible. However, an acceleration in the performance potential of fluid power systems dictated a need for much better lubricating requirements that could be satisfied only by oil-based fluids.

Apart from isolated segments of basic research, little progress was made in developing suitable FRHFs until the end of World War II. During the war, tragic incidents related to hydraulic fluid fires and major property losses at steel mills and foundries graphically illustrated the urgent need for something to be done. Similar incidents in captive environments such as coal mines during the rapid post-war industrial expansion helped motivate a major joint research effort between government and industry. This work was directed at developing fluids that could replace oil-based hydraulic fluids at a reasonable cost and with no significant reduction in hydraulic system performance. Two basic approaches were undertaken. One involved the introduction of water into the fluid to act as a "snuffer" if the fluid ignited. The other involved synthetic, non-aqueous products whose chemistry resisted burning or generated products of combustion that helped extinguish any flame.

Commercial products in both categories evolved during the 1950s and '60s and are still in use today. In the early 1970s, an additional synthetic type of fluid was introduced to address many of the drawbacks inherent in the earlier types. Since the introduction of each type, many improvements have been made in fire resistance, anti-wear properties, and overall quality.

Where we are

Water glycol and invert emulsion constitute the major fluid types of water-containing products. Water glycol is a true solution of a glycol (such as ethylene glycol) in water, along with a variety of additives to impart viscosity, corrosion protection, and anti-wear properties. A shear-stable thickener, which has improved over the years, represents the novel technology aspect of the fluid. Water glycol contains approximately 40% water. Despite a number of drawbacks, water glycol is the dominant FRHF on the market today and is used in a wide variety of applications.

An invert emulsion also contains approximately 40% water but is a stable emulsion of water dispersed in oil. The outer phase, oil, represents the wetting surface; the inner phase, water, provides the fire retardant-element. Oil-soluble additives provide anti-wear properties, corrosion protection, and emulsion stability. Inverts, at one time, were commonly used but are losing favor in industry today.

Synthetic fluids initially were represented by a class of chemical compounds known as phosphate esters, which are reaction products between phosphoric acid and aromatic ring-structure alcohols. These fluids are extremely fire resistant and have widespread industrial use, as well as military and aircraft service. However, their popularity has declined because of environmental, cost, and compatibility factors.

The other type of synthetic fluids in use are synthetic hydrocarbons, more specifically, polyol esters. These fluids are the reaction products between long-chain fatty acids (derived from animal and vegetable fats) and synthesized organic alcohols. These products contain additives to impart anti-wear properties, corrosion protection, and viscosity modification. Fire resistance results from a combination of high thermal properties and physical characteristics. This is the most recent category of FRHFs and has gained widespread and growing use.